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On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes

  1. Title statementOn the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes [electronic resource] / by Terrance John Hadlington.
    PublicationCham : Springer International Publishing : Imprint: Springer, 2017.
    Phys.des.XIX, 243 p. 170 illus., 59 illus. in color. online resource.
    ISBN9783319518077
    EditionSpringer Theses, Recognizing Outstanding Ph.D. Research, ISSN 2190-5053
    ContentsGeneral Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.
    Notes to AvailabilityPřístup pouze pro oprávněné uživatele
    Another responsib. SpringerLink (Online service)
    Subj. Headings Chemistry. * Inorganic chemistry. * Organometallic chemistry. * Catalysis.
    Form, Genre elektronické knihy electronic books
    CountryNěmecko
    Languageangličtina
    Document kindElectronic books
    URLPlný text pro studenty a zaměstnance UPOL
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    This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.

    General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.

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