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Techniques in inorganic chemistry

  1. Title statementTechniques in inorganic chemistry / edited by John P. Fackler, Jr., Larry R. Falvello
    PublicationBoca Raton, FL : CRC Press/Taylor & Francis, [2011]
    Copyright notice date©2011
    Phys.des.1 online zdroj (x, 209 stran, 16 nečíslovaných stran obrazových příloh) : ilustrace (některé barevně)
    ISBN9781439815151 (online)
    1439815151 (online)
    Internal Bibliographies/Indexes NoteObsahuje bibliografické odkazy a rejstřík
    ContentsChapter 1 Current Developments in Small-Molecule X-Ray Crystallography -- Chapter 2 X-Ray Powder Diffraction Characterization of Polymeric Metal Diazolates -- Chapter 3 Single Crystal Neutron Diffraction for the Inorganic Chemist -- A Practical Guide -- Chapter 4 Adventures of Quantum Chemistry in the Realm of Inorganic Chemistry -- Chapter 5 NMR Techniques for Investigating the Supramolecular Structure of Coordination Compounds in Solution -- Chapter 6 Pressure-Induced Change of d-d Luminescence Energies, Vibronic Structure, and Band Intensities in Transition Metal Complexes.
    Notes to AvailabilityPřístup pouze pro oprávněné uživatele
    NoteZpůsob přístupu: World Wide Web
    DefektyeBooks on EBSCOhost
    Another responsib. Fackler, John P. (editor)
    Falvello, Larry (editor)
    Subj. Headings anorganická chemie inorganic chemistry
    Form, Genre elektronické knihy electronic books
    Conspect546 - Anorganická chemie
    UDC 546 , (0.034.2:08)
    CountryFlorika
    Languageangličtina
    Document kindElectronic sources
    URLhttp://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&AN=337570
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    Inorganic chemistry continues to generate much current interest due to its array of applications, ranging from materials to biology and medicine. Techniques in Inorganic Chemistry assembles a collection of articles from international experts who describe modern methods used by research students and chemists for studying the properties and structures of inorganic chemicals. The book begins by examining developments in small-molecule x-ray crystallography. It identifies some of the major advances, discusses curren attitudes toward crystallography and its uses, and considers challenges and future prospects. It then examines how ab initio x-ray powder diffraction (XRPD) methods are used to determine structure, with discussions on metal pyrazolates, metal imidazolates, and metal pyrimidinolates. This is followed by a description of single-crystal neutron diffraction, a powerful structural technique. The text highlights what can presently be achieved in neutron diffraction and discusses future applications of neutron scattering. Reflecting the popularity of density functional calculations, the book includes a chapter that focuses on quantum chemistry. It examines the latest computational techniques and describes how these techniques can be applied to solve a wide range of real-world problems encountered in the realm of inorganic chemistry and particularly in transition metal chemistry. It also explains the intelligent use of quantum chemical methods for the determination of molecular structure, reactivity, and spectra of coordination and organometallic compounds. Lastly, the text explores important spectroscopic approaches. It first describes intermolecular nuclear Overhauser effect (NOE) NMR experiments and diffusion experiments, offering examples that demonstrate theoretical aspects of the methodology. The final chapter summarizes recent experimental and theoretical, work on pressure effects on the d-d and luminescence spectra of transition metal complexes. Derived from select articles in Comments on Inorganic Chemistry, this volume provides a solid background in the array of techniques available in the researcher's toolkit --Book Jacket.

    Chapter 1 Current Developments in Small-Molecule X-Ray Crystallography -- Chapter 2 X-Ray Powder Diffraction Characterization of Polymeric Metal Diazolates -- Chapter 3 Single Crystal Neutron Diffraction for the Inorganic Chemist -- A Practical Guide -- Chapter 4 Adventures of Quantum Chemistry in the Realm of Inorganic Chemistry -- Chapter 5 NMR Techniques for Investigating the Supramolecular Structure of Coordination Compounds in Solution -- Chapter 6 Pressure-Induced Change of d-d Luminescence Energies, Vibronic Structure, and Band Intensities in Transition Metal Complexes.

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